Material - Safety - Data Sheet (MSDS) 1/7 for Ansmann Lithium-Manganese-Dioxide (Li-metal) Batteries single cells and multi-cell battery packs Date of issue: 2011 - 07 - 06 The information contained within is provided as a service to our customers and Revision no: 5 for their information only. The information and recommendations set forth herein Revision date: 2013 - 11 - 07 are made in good faith and are believed to be accurate at the date of preparation. Editor: Ansmann AG ANSMANN AG makes no warranty expressed or implied. 1. Product and Supplier Identification Product names: ANSMANN Lithium Photo Battery ANSMANN Lithium Button Cell ANSMANN EXTREME Lithium Designation: Lithium Metal Battery Models / types: CR123, CR2, CR-P2, 2CR5 CR1216, CR1220, CR1225, CR1616, CR1620, CR1632 CR2016, CR2025, CR2032, CR2330, CR2430, CR2450, CR2477 E-Block, 9V, (CR-V9, ER9V) Electrochemical system: Li-MnO (Lithium-Manganse-Dioxide) 2 Supplier: Germany ANSMANN AG Address: Industriestrae 10 97959 Assamstadt Germany Phone / Facsimile: + 49 (0) 6294 42040 / + 49 (0) 6294 420444 Home / email: ansmann.de / info ansmann.de USA ANSMANN USA Corporation Address: 1001 Lower Landing Rd. Ste 101 Blackwood, NJ08012 USA Phone / Facsimile: +1 973 4395244 1012 / +1 973 2062006 email: USA ansmann.de United Kingdom ANSMANN Energy (UK) LTD Address: Units 19/20, Maple Park Essex Road Hoddesdon Hertfordshire EN11 0EX UK Phone / Facsimile: +44 (0) 870 609 2233 / +44 (0) 870609 2234 email: UK ansmann.de Hong Kong ANSMANN Energy Int. LTD. Address: Unit 3117-18, 31/F Tower 1 Millenium City 1 No. 388 Kwun Tong Road Kwun Tong, kowloon Hong-Kong hongkong ansmann.de China HuiZhou City ANSMANN Trading Co. LTD Address: Da Lian Industrial Park, Rengtu Village Ruhu Town Huicheng District, 516169 Huizhou City Guangdong, China china ansmann.de Sweden ANSMANN Nordic AB Address: Victor Hasselblads Gata 11, 421 31 Vstra Frlunda, Sweden nordic ansmann.de EMERGENCY CONTACT: For chemical emergency only (spill, leak, fire, exposure or accident) call CHEMTREC at: 800-424-9300 within the USA and Canada +1 703-527-3887 outside the USA and Canada Non-emergency calls cannot be serviced at this number. 2. Product and Supplier Identification The Lithium-Manganese-Dioxide batteries described in this MSDS are hermetically sealed units, which are not hazardous when used according to the recommendations of the manufacturer. Under normal condition of use of the batteries, the electrode materials and the liquid electrolyte they contained are non-reactive provided the battery integrity is maintainted. Risk of exposure exists only in case of mechanical, electrical or thermal abuse. Thus the batteries should not short circuited, recharged, punctured, incinerated, crushed, immersed in water, force discharged or exposed to temperatures above the temperature range of the cell or battery. In these cases there is risk of fire or explosion.Material - Safety - Data Sheet (MSDS) 2/7 for Ansmann Lithium-Manganese-Dioxide (Li-metal) Batteries single cells and multi-cell battery packs 3. Composition and Informations on Ingredients Each cell consists of a hermetically sealed metallic container containing a number of chemicals and materials of construction of which the following could potentially be hazardous upon release. Ingredient Content CAS No. CHIP Classification F C Lithium (Li) 2 - 5% 7439-93-2 R14/15 R34 S43C S45 S8 Xn Manganese Dioxide 15 - 45% 1313-13-9 R20/22 (MnO ) S25 2 Xi Propylene Carbonate <10% 108-32-7 R36 S24/25 Lithium trifluoromethyl Xi sulfonate <5% 33454-82-9 R36/37/38 (only Photo Batteries) S26 S37/39 O Xn Lithium Perchlorate <1% 7791-03-9 R20/22 R36/37/38 R9 (only Button Cells) S17 S26 S27 S36/37/38 Graphite, synthetic 3 - 10% 7440-44-0 S22 S24/25 (only Button Cells) stainless steel 30 - 75% 7439-89-6 plastic 0 -10% Remark: The weight of metallic lithium per cell is: 1g The weight of metallic lithium per battery (2CR5, CR-P2) is: 2g 4. First Aid Measures Inhalation: Provide fresh air. In severe cases obtain medical attention. Skin Contact: Wash off skin thoroughly with water. Remove contaminated clothing and wash before re-use. In severe cases obtain medical attention. Eye Contact: Irrigate thoroughly with water for at least 15 minutes. Lifting upper and lower lids, until no evidence of the chemical remains. Obtain medical attention. Ingestion: Wash out mouth thoroughly with water. Do not induce vomiting or give food or drink. Seek medical attention immediately. Further treatment: All cases of eye contamination, persistent skin irritation and casualities who have swallowed this substance or been affected by breathing its vapours should be seen by a doctor. 5. Product and Supplier Identification CO extinguishers or, even preferably, copious quantities of water or water-based foam, can be used to cool 2 down burning Li- MnO cells and batteries, as long as the extent of the fire has not progressed to the point 2 that the lithium metal they contain is exposed (marked by deep red flames). Do not use for this purpose sand, dry powder or soda ash, graphite powder or fire blankets. Use only metal (Class D) extinguishers on raw lithium. Extinguishing media Use water or CO on burning Li-MnO cells or batteries and class D fire 2 2 extinguishing agent only on raw lithium.