MSDS00153 MATERIAL SAFETY DATA SHEET / SAFETY DATA SHEET SECTION I PRODUCT AND COMPANY IDENTIFICATION Product Description 9-Volt Lithium Manganese Dioxide Batteries (TFSi Style) Product Identification Manufacturer Ultralife Corporation 24 Hour ChemTrec Name/Address 2000 Technology Parkway Emergency 800-424-9300 (US) Newark, NY 14513 Contact 703-527-3887 (International) Technical Contact 800-332-5000 Issue Date 02 FEB 10 Prepared By John Diggory Revision Date: 05 OCT 11 Section II - HAZARD IDENTIFICATION Hazard This Ultralife battery product meets the definition of an article. Under the Globally Harmonized System of Classification and Labeling of Chemicals (GHS), Articles as Classification defined in the Hazard Communication Standard (29 CFR 1910.1200) of the Occupational Safety and Health Administration of the United States of America, or by similar definition, are outside the scope of the system. Rev. 2 (2007) Part 1.3.2.1.1 Hazard/Caution Do not open or disassemble. Statements Do not expose to fire or open flame. Do not mix with batteries of varying sizes, chemistries or types. o o Do not puncture, deform, incinerate or heat above 60 C (140 F). The materials contained in this product may only represent a hazard if the integrity of the cell or battery is compromised physically or electrically abused. SECTION III - COMPOSITION - INGREDIENTS/IDENTITY INFORMATION Under normal use conditions, cells and batteries do not emit hazardous or regulated substances. Component CAS Number EINECS Number % by Wt. Manganese Dioxide, MnO 1313-13-9 215-202-6 60-70 2 Lithium Metal, Li 7439-93-2 231-102-5 5-7 Propylene Carbonate, C H O 108-32-7 203-572-1 1-10 4 6 3 Ethylene Carbonate, C H O 96-49-1 202-510-0 1-5 3 4 3 Ethylene Glycol Dimethyl Ether 110-71-4 203-794-9 1-6 (1,2-Dimethoxyethane), C H O 4 10 2 Ethyl Methyl Carbonate,C4H8O3 623-53-0 NA 1-6 Bis (Trifluoromethane) Sulfonimide 90076-65-6 415-300-0 2-4 Lithium (LiTFSi) Non-hazardous components NA NA 1-20 Depending on product configuration, components used to assemble battery packs (e.g. housings, electronic components and wiring) may contain additional hazardous materials. ANY PHOTOCOPY MUST BE OF THIS ENTIRE DOCUMENT MSDS00153 Page 1 of 6 Rev.: A Date: 05 OCT 11 MSDS00153 SECTION IV - FIRST AID MEASURES Avoid inhaling any vented gases. Inhalation Remove to fresh air immediately. If breathing is difficult, seek emergency medical attention. Ingestion Consult a physician or local poison control center immediately Skin Contact Exposure to materials from a ruptured or otherwise damaged cell or battery may cause skin irritation. Flush immediately with water and wash affected area with soap and water. Eye Contact Exposure to materials from a ruptured or otherwise damaged cell or battery may cause eye irritation. Flush immediately with copious amounts of water for at least 15 minutes consult a physician immediately. SECTION V - FIRE FIGHTING MEASURES Extinguishing Copious amounts of cold water or water-based foam may be used to cool burning Media cells or batteries. Do not use warm or hot water. A carbon dioxide (CO ) extinguisher is also effective. 2 For fires involving exposed, raw lithium metal (characterized by deep red flames), use only metal (Class D) fire extinguishers. Special Fire Use a positive pressure self-contained breathing apparatus (SCBA) if cells or Fighting batteries are involved in a fire. Procedures Full fire fighting protective clothing is necessary. During water application, caution is advised as burning pieces of flammable particles may be ejected from the fire. Unusual Fire Cells or batteries that are damaged, opened or exposed to excessive heat/fire may and Explosion flame or leak potentially hazardous organic vapors. Hazard SECTION VI - ACCIDENTAL RELEASE MEASURES In the event a cell or battery is crushed releasing its contents, rubber gloves must be used to handle all battery components. Avoid inhalation of any vapors that may be emitted. Damaged batteries that are not hot or burning should be placed in a sealed plastic bag or container. ANY PHOTOCOPY MUST BE OF THIS ENTIRE DOCUMENT MSDS00153 Page 2 of 6 Rev.: A Date: 05 OCT 11