Material Safety Data Sheet MSDS 2.001.007 Lithium primary cylindrical cell (coiled) 1. Identification of the product and of the company undertaking Product details Trade name: Lithium primary cylindrical cell (coiled) Voltage: 3.0 V (or multiples of this in case of multi-cell configurations) Electrochemical system: Lithium metal organic electrolyte manganese dioxide Anode (negative): Lithium metal Cathode (positive): Manganese dioxide Type: Lithium content per cell/battery: CR 2/3 AH 0.58 g CR 123 A 0.58 g CR 2 0,26 g CR P2 1.16 g (6.0 V battery) Supplier details Address: VARTA Microbattery GmbH Daimlerstr. 1 D-73479 Ellwangen/Jagst Germany Emergency telephone number: +49 7961 921 110 (VAC) Legal Remark (U.S.A.) Material Safety Data Sheets (MSDS) are a sub-requirement of the Occupational Safety and Health Administration (OSHA) Hazard Communication Standard, 29 CFR Subpart 1910.1200. This Hazard Communication Standard does not apply to various subcategories including anything defined by OSHA as anarticl. OSHA has definedarticl as a manufactured item other than a fluid or particle (i) which is formed to a specific shape or design during manufacture (ii) which has end use function(s) dependent in whole or in part upon its shape or design during end use and (iii) which under normal conditions of use does not release more than very small quantities, e.g. minute or trace amounts of a hazardous chemical, and does not pose a physical hazard or health risk to employees. Because all of our batteries are defined asarticle, they are exempted from the requirements of the Hazard Communication Standard. Legal remark (EU) These batteries are no substances or preparations according to Regulation (EC) No 1907/2006 EC. Instead they have to be regarded as articles, no substances are intended to be released during handling. Therefore there is no obligation to supply a MSDS according to Regulation (EC) 1907/2006, Article 31. General remark This Safety Information is provided as a service to our customers. The details presented are in accordance with our present knowledge and experiences. They are no contractual assurances of product attributes. Page no.: 1 of 6 VARTA Microbattery GmbH Daimlerstrae 1 Edition: 09.01.2012 Electronically generated document - no signature required. 73479 Ellwangen Germany Version: 06 Fo 175 Material Safety Data Sheet MSDS 2.001.007 2. Hazards identification The battery is sealed hermetically. Thus, the ingredients have no hazard potential, except the battery is violated or dismantled. If in case of mistreatment the ingredients are released, a spontaneously flammable gas mixture may be released under certain circumstances (measures according to chapter 4 to 6). Attention: If batteries are treated wrong the danger of burns or bursts occurs. Batteries must not be heated above 100C or incinerated. The battery contents must not get in contact with water. If the negative electrode gets in contact with water or humidity hydrogen gas is formed, which may inflame spontaneously. 3. Composition/information on ingredients Ingredients Contents CAS No. Classification R Phrases Material 2 - 5 % 7439-93-2 F 14/15 Lithium C 34 13 - 40 % 1313-13-9 Xn 20/22 Manganese dioxide < 10 % 108-32-7 Xi 36 Propylene carbonate < 10 % 110-71-4 F 60 1,2-Dimethoxy ethane Repr. Cat. 2 61 Xn 11 19 20 < 5 % 33454-82-9 Xi 36/37/38 Lithium trifluoromethyl sulfonate Heavy Metals Contents CAS No. Material < 1 mg/kg 7440-43-9 Cadmium < 10 mg/kg 7439-92-1 Lead Mercury < 0,1 mg/kg 7439-97-6 (none intentionally introduced, see Chapter 12) < 5 mg/kg Hexavalent Chromium (Cr6+) Other Ingredients Contents CAS No. Material 33 74 % Steel and nickel 3 10 % Plastic 4. First-aid measures Measures at accidental release After inhalation: Fresh air. Seek for medical assistance. After skin contact: Remove solid particles immediately. Flush affected areas with plenty of water (at least 15 min.). Remove contaminated cloth immediately. Seek for medical assistance. After eye contact: Flush the eye gently with plenty of water (at least 15 min.). Seek for medical assistance. After ingestion: Drink plenty of water. Avoid vomiting. Seek for medical assistance. No trials for neutralization. Page no.: 2 of 6 VARTA Microbattery GmbH Daimlerstrae 1 Edition: 09.01.2012 Electronically generated document - no signature required. 73479 Ellwangen Germany Version: 06 Fo 175